研究成果 [After 2019]

通讯或第一作者论文：

1. Hua, T.^‡; Cao, X.^‡; Miao, J.^‡; Yin, X.; Chen, Z.; Huang, Z.; Yang, C.* Deep-Blue Organic Light-Emitting Diodes for Ultrahigh-Definition Displays, Nat. Photonics 2024, accepted.

2. Huang, X.^‡; Liu, J.^‡; Xu, Y.; Chen, G.; Huang, M.; Yu, M.; Lv, X.; Yin, X.; Zou, Y.; Miao, J.; Cao, X.*; Yang, C.* B‒N Covalent Bond-Involved Π-Extension of Multiple Resonance Emitters Enables High-Performance Narrowband Electroluminescence, Natl. Sci. Rev. 2024, 11, nwae115.

3. Ye, Z.; Wu H.; Xu Y.; Hua T.; Chen G.; Chen Z.; Yin X.; Huang M.; Xu K.; Song X.; Huang Z.; Lv X.; Miao J.; Cao X.*; Chuluo Yang.* Deep-Blue Narrowband Hetero[6]helicenes Showing Circularly Polarized Thermally Activated Delayed Fluorescence Toward High-Performance OLEDs, Adv. Mater. 2023, 36, 202308314.

4. Jing, Y.-Y.; Li, N.; Cao, X.*; Wu, H.; Miao, J.; Chen, Z.; Huang, M.; Wang, X.*; Hu, Y.; Zou, Y.; Yang, C.* Precise Modulation of Multiple Resonance Emitters toward Efficient Electroluminescence with Pure-Red Gamut for High-Definition Displays, Sci. Adv. 2023, 9, eadh8296.

5. Huang, Z.; Xie, H.; Miao, J.; Wei, Y.; Zou, Y.; Hua, T.; Cao, X.*; Yang, C.* Charge Transfer Excited State Promoted Multiple Resonance Delayed Fluorescence Emitter for High-Performance Narrowband Electroluminescence, J. Am. Chem. Soc. 2023, 145, 12550-12560.

6. Cao, X.*; Pan, K.; Miao, J.; Lv, X.; Huang, Z.; Ni, F.; Yin, X.; Wei, Y.*; Yang, C.* Manipulating Exciton Dynamics toward Simultaneous High-Efficiency Narrowband Electroluminescence and Photon Upconversion by a Selenium-Incorporated Multiresonance Delayed Fluorescence Emitter, J. Am. Chem. Soc. 2022, 144, 22976-22984.

7. Yang, Y.^‡; Li, N.^‡; Miao, J.; Cao, X.*; Ying, A.; Pan, K.; Lv, X.; Ni, F.; Huang, Z.; Gong, S.; Yang, C.* Chiral Multi-Resonance TADF Emitters Exhibiting Narrowband Circularly Polarized Electroluminescence with EQE of 37.2%, Angew. Chem. Int. Ed. 2022, e202202227.

8. Lv, X.; Miao, J.; Liu, M.; Peng, Q.; Zhong, C.; Hu, Y.; Cao, X.*; Wu, H.; Yang, Y.; Zhou, C.; Ma, J.; Zou, Y.; Yang, C.* Extending the π-Skeleton of Multi-Resonance TADF Materials towards High-Efficiency Narrowband Deep-Blue Emission, Angew. Chem. Int. Ed. 2022, e202201588.

9. Jiang, P.^‡; Miao, J.^‡; Cao, X.*; Xia, H.; Pan, K.; Hua, T.; Lv, X.; Huang, Z.; Zou, Y.; Yang, C*. Quenching-Resistant Multiresonance TADF Emitter Realizes 40% External Quantum Efficiency in Narrowband Electroluminescence at High Doping Level, Adv. Mater. 2022, 34, 2106954.

10. Wei, Y.; Pan, K.; Cao, X.*; Li, Y.; Zhou, X.; Yang, C.* Multiple Resonance Thermally Activated Delayed Fluorescence Sensitizers Enable Green-to-Ultraviolet Photon Upconversion: Application in Photochemical Transformations, CCS Chem. 2022, 4, 3852-3863.

11. Wei Y.; An K.; Xu X.; Ye Z.; Yin X.; Cao, X.*; Yang, C.* Π-Radical Photosensitizer for Highly Efficient and Stable Near-Infrared Photon Upconversion, Adv. Opt. Mater. 2023, 2301134.

12. Huang X.; Xu Y.; Miao J.; Jing Y.-Y.; Wang S.; Ye Z.; Huang Z.; Cao, X.*; Yang, C. Donor-Modified Multiple Resonance Emitters with Accelerated Reverse Intersystem Crossing Towards High-Efficiency and Narrowband Deep-Blue OLEDs, J. Mater. Chem. C. 2023, 11, 11885.

13. Hao, Z.; Li, N.; Miao, J.; Huang, Z.; Lv, X.; Cao, X.* Chiral Sulfoximine-Based TADF Emitter for Circularly Polarized Luminescence and Highly Efficient OLEDs, Chem. Eng. J. 2023, 454, 140070.

14. Jing Y.-Y.; Yang Y.; Li N.; Ye Z.; Wang X.*; Cao, X.*; Yang, C. Indolo[3,2-b]indole-Based Multi-Resonance Emitters for Efficient Narrowband Pure-Green Organic Light-Emitting Diodes, Luminescence 2023, DOI: 10.1002/bio.4624.

15. Wei, Y.; Xian, H.; Lv, X.; Ni, F.; Cao, X.*; Yang, C*. Triplet–Triplet Annihilation Upconversion with Reversible Emission-Tunability Induced by Chemical-Stimuli: A Remote Modulator for Photocontrol Isomerization, Mater. Horiz. 2021, 8, 606-611.

16. Jiang, P.^‡; Zhan, L.^‡; Cao, X*.; Lv, X.; Gong, S.*; Chen, Z.; Zhou, C.; Huang, Z.; Ni, F.; Zou, Y.; Yang, C.* Simple Acridan-Based Multi-Resonance Structures Enable Highly Efficient Narrowband Green TADF Electroluminescence, Adv. Opt. Mater. 2021, 9, 2100825.

17. Zhou, C.; Cao, C.; Yang, D.; Cao, X.*; Liu, H.; Ma, D.; Lee, C.-S.*; Yang, C.* Highly Efficient Red Thermally Activated Delayed Fluorescence Emitters by Manipulating The Molecular Horizontal Orientation, Mater. Chem. Front. 2021, 5, 3209-3215.

18. Yang, Y.; Xiao, R.; Cao, X.*; Chen, Z.; Lv, X.; Zhang, Y.*; Gong, S.; Zou, Y.; Yang, C. Phenoxazine-Dibenzothiophene Sulfoximine Emitters Featuring Both Thermally Activated Delayed Fluorescence and Aggregation Induced Emission, Molecules 2021, 26, 5243.

19. Wei, Y.; Li, Y.; Li, Z.; Xu, X.; Cao, X.*; Zhou, X.*; Yang, C.* Efficient Triplet–Triplet Annihilation Upconversion in Solution and Hydrogel Enabled by an S-T Absorption Os(II) Complex Dyad with an Elongated Triplet Lifetime, Inorg. Chem. 2021, 60, 19001-19008.

20. Lv, X.; Cao, X.*; Wu, H.; Lin, H.; Ni, F.; Huang, H.; Zou, Y.; Yang, C.* Realize Efficient Organic Afterglow From Simple Halogenated Acridan Derivatives, Chem. Eng. J. 2021, 419, 129598.

21. Cao, X.; Chen, Z.; Gong, S.; Pan, K.; Zhou, C.; Huang, T.; Chai, D.; Zhan, Q.; Li, N.; Zou, Y.; Liu, H.; Yang, C.* Designing Versatile Sulfoximine as Accepting Unit to Regulate the Photophysical Properties of TADF Emitters towards High-Performance OLEDs, Chem. Eng. J. 2020, 399, 125648.

22. Xiao, R.; Xiang, Y.; Cao, X.*; Li, N.; Huang, T.; Zhou, C.; Zou, Y.; Xie, G.; Yang, C.* Star-Shaped Thermally Activated Delayed Fluorescence Emitters with A Tri-Armed Arylsulfonic Acceptor for Efficient Solution Processed Organic Light Emitting Diodes, J. Mater. Chem. C. 2020, 8, 5580-5586.

23. Naguib, H.; Cao, X.*; Gao, H.* Synthesize Hyperbranched Polymers Carrying Two Reactive Handles via CuAAC Reaction and Thiol-Ene Chemistry, Macromol. Chem. Phys. 2019, 220, 1900221.

共同作者论文：

1. Huang, H.; Li, N.; Li, W.; Mo, X.; Cao, X.; Miao, J.; Yin, X.*; Yang, C. Synergistic Modulation of Excited State Ingredients and Chiroptical Activity for High‐Performance Pure‐Green Circularly Polarized Electroluminescence, Adv. Funct. Mater., 2024, 2403191.

2. Wang, C.; Hu, N.; Chen, Z.; Chen, Y.; Chang, P.; Han, C.*; Cao, X.; Xu, H.* Efficient Narrowband Organic Light-Emitting Diodes Based on B,O Embedded Multi-Resonance Emitters Containing B-N Covalent Bonds, Chem. Eng. J., 2024, 488, 150785.

3. Miao, J.; Chen, G.; He, J.; Xiao, Z.; Song, X.; Wang, M.; Huang, M.; Li, K.; Cao, X.; Zou, Y.*; Yang, C. Modulation of Carbazole/Phenol Resonant Partners within Diboron-Based Multi-Resonance Emitters Enable High-Performance Narrowband Green to Red OLEDs, Adv. Funct. Mater., 2024, 2316323.

4. Wu, L.; Huang, Z.*; Miao, J.; Wang, S.; Li, X.*; Li, N.; Cao, X.; Yang, C.* Orienting Group Directed Cascade Borylation for Efficient One-Shot Synthesis of 1,4-BN-Doped Polycyclic Aromatic Hydrocarbons as Narrowband Organic Emitters, Angew. Chem. Int. Ed., 2024, 63, e202402020.

5. Zou, Y.; Yu, M.; Xu, Y.; Xiao, Z.; Song, X.; Hu, Y.; Xu, Z.; Zhong, C.; He, J.; Cao, X.; Li, K.; Miao, J.; Yang, C.* Acceleration of Reverse Intersystem Crossing in Multi-Resonance TADF Emitter, Chem 2024, 10, 1485-1501.

6. Hua, T.^‡; Li, N.^‡; Huang, Z.; Zhang, Y.*; Wang, L.; Chen, Z.; Miao, J.; Cao, X.; Wang, X.*; Yang, C.* Narrowband Near-Infrared Multiple-Resonance Thermally Activated Delayed Fluorescence Emitters towards High-Performance and Stable Organic Light-Emitting Diodes, Angew. Chem. Int. Ed. 2024, 63, e202318433.

7. Huang, H.; Li, N.; Fu, S.; Mo, X.; Cao, X.; Yin, X.*; Yang, C. Pure Polycyclic Aromatic Hydrocarbon Isomerides with Delayed Fluorescence and Anti-Kasha Emission: High-Efficiency Non-Doped Fluorescence OLEDs, Adv. Sci. 2023, 10, 2304204.

8. Wang, S.; Xu, Y.; Miao, J.; Hua, T.; Cao, X.; Li, N.; Huang, Z.*; Yang, C. Peripheral Decoration of Multi-Resonance TADF Emitter for Narrowband Blue OLEDs, Chem. Eng. J. 2023, 471, 144664.

9. Ying, A.; Zhan, L.; Tan, Y.; Cao, X.; Yang, C.; Gong, S.* Copper(I) Complexes with Planar Chirality Realize Efficient Circularly Polarized Electroluminescence, Sci. China Chem. 2023, 66, 2274–2282.

10. He, J.; Xu, Y.; Luo, S.; Miao, J.; Cao, X.; Zou, Y.* Phenoxazine and Phenothiazine Embedded Multi-Resonance Emitters for Highly Efficient Pure-Red OLEDs with Improved Color Purity, Chem. Eng. J. 2023, 471, 144565.

11. Wu, Y.; Liu, X.; Liu, J.; Yang, Y.; Han, S.; Yang, D.; Cao, X.; Ma, D.; Bin, Z.; You, J.* Geometry Engineering of a Multiple Resonance Core Via a Phenyl-Embedded Strategy Toward Highly Efficient Narrowband Blue OLEDs, Mater. Horiz. 2023, 10, 3785-3790.

12. Zou, Y.; He, J.; Li, N.; Hu, Y.; Luo, S.; Cao, X.; Yang, C.* Precisely Regulating the Double-Boron-Based Multi-Resonance Framework towards Pure-Red Emitters: High-Performance OLEDs with CIE Coordinates Fully Satisfying the BT. 2020 Standard, Mater. Horiz. 2023, 10, 3712-3718.

13. Wang, T.; Yin, X.; Cao, X.; Yang, C.* A Simple Approach to Solution-Processible Small-Molecule Multi-Resonance TADF Emitters for High-Performance Narrowband OLEDs, Angew. Chem. Int. Ed. 2023, 62, e202301988.

14. Wu, Y.; Ni, F.; Chen, Z.; Yang, W.; Xiang, Y.; Gong, S.; Cao, X.; Yang, C.* Aggregation-Dependent Thermally Activated Delayed Fluorescence Emitters: AIE or ACQ? Adv. Opt. Mater. 2023, 11, 2300186.

15. Li, N.; Chen, Z.; Zhou, C.; Ni, F.; Huang, Z.; Cao, X.; Yang, C.* Versatile Host Materials for Both D–A-Type and Multi-Resonance TADF Emitters toward Solution-Processed OLEDs with Nearly 30% EQE, Adv. Mater. 2023, 35, 2300510.

16. Zhan, L.; Chen, T.; Zhong, C.; Cao, X.; Zhang, Y.; Zou, Y.; Bin, Z.; You, J.; Zhang, D.; Duan, L.; Yang, C.; Gong, S.* Luminescent Gold(III) Exciplexes Enable Efficient Multicolor Electroluminescence, Sci. China Chem. 2023, 66, 3213-3222.

17. Hu, Y.; Miao, J.; Zhong, C.; Zeng, Y.; Gong, S.; Cao, X.; Zhou, X.; Gu, Y.; Yang, C.* Peripherally Heavy-Atom-Decorated Strategy Towards High-Performance Pure Green Electroluminescence with External Quantum Efficiency over 40%, Angew. Chem. Int. Ed. 2023, 62, e202302478.

18. Zou, Y.; Yu, M.; Miao, J.; Huang, T.; Liao, S.; Cao, X.; Yang, C.* Dynamic Bond Interactions Fine-Tune the Properties of Multiple Resonance Emitters towards Highly Efficient Narrowband Green OLEDs, Chem. Sci. 2023, 14, 3326-3331.

19. Chen, Z.; Huang, M.; Zhong, C.; Cao, X.; Xie, G.; Gong, S.; Yang, C.* Cascade Chirality Transfer Through Diastereomeric Interaction Enables Efficient Circularly Polarized Electroluminescence, Adv. Funct. Mater. 2023, 33, 2215179.

20. Hu, Y. X.^‡; Miao, J.^‡; Hua, T.; Huang, Z.;Qi, Y.; Zou, Y.; Qiu, Y.; Xia, H.; Liu, H.; Cao, X.; Yang, C.* Efficient Selenium-Integrated TADF OLEDs with Reduced Roll-Off, Nat. Photonics 2022, 16, 803-810.

21. Zou, Y.; Hu, J.; Yu, M.; Miao, J.; Xie, Z.; Qiu, Y.; Cao, X.; Yang, C.* High Performance Narrowband Pure-Red OLEDs with External Quantum Efficiencies up to 36.1% and Ultra-low Efficiency Roll-off, Adv. Mater. 2022, 34, 2201442.

22. Hua, T.; Miao, J.; Xia, H.; Huang, Z.*; Cao, X.; Li, N.; Yang, C.* Sulfone-Incorporated Multi-Resonance TADF Emitter for High-Performance Narrowband Blue OLEDs with EQE of 32%, Adv. Funct. Mater. 2022, 2201032.

23. Xie, Z.^‡; Cao, C.^‡; Zou, Y.*; Cao, X.; Zhou, C.; He, J.; Lee, C. S.*; Yang, C.* Molecular Engineering Enables TADF Emitters Well Suitable for Non-Doped OLEDs with External Quantum Efficiency of Nearly 30%, Adv. Funct. Mater. 2022, 32, 2112881.

24. Hua, T.^‡; Liu, Y.-C.^‡; Huang, C.-W.; Li, N.; Zhou, C.; Huang, Z.*; Cao, X.; Wu, C.-C.*; Yang, C.* High-Efficiency and Low Roll-Off Deep-Blue OLEDs Enabled by Thermally Activated Delayed Fluorescence Emitter with Preferred Horizontal Dipole Orientation, Chem. Eng. J. 2022, 433, 133598.

25. Ying, A.; Huang, Y.-H.; Lu, C.-H.; Chen, Z.; Lee, W.-K.; Zeng, X.; Chen, T.; Cao, X.; Wu, C.-C.*; Gong, S.*; Yang, C. High-Efficiency Red Electroluminescence Based on a Carbene–Cu(I)–Acridine Complex, ACS Appl. Mater. Interfaces. 2021, 13, 13478–13486.

26. Yang, W.; Yang, Y.; Cao, X.; Liu, Y.; Chen, Z.; Huang, Z.; Gong, S.; Yang, C.* On-Off Switchable Thermally Activated Delayed Fluorescence Controlled By Multiple Channels: Understanding The Mechanism Behind Distinctive Polymorph-Dependent Optical Properties, Chem. Eng. J. 2021, 415, 128909.

27. Xu, T.*; Xie, G.*; Huang, T.; Liu, H.; Cao, X.; Tang, Y.; Yang, C.* Solution-Processed Multiple Exciplexes Via Spirofluorene And S-Triazine Moieties For Red Thermally Activated Delayed Fluorescence Emissive Layer OLEDs, Org. Electron. 2021, 96, 106184.

28. Xiao, Z.; Li, N.; Yang, W.; Huang, Z.*; Cao, X.; Huang, T.; Chen, Z.; Yang, C.* Saccharin-Derived Multifunctional Emitters Featuring Concurrently Room Temperature Phosphorescence, Thermally Activated Delayed Fluorescence and Aggregation-Induced Enhanced Emission, Chem. Eng. J. 2021, 419, 129628.

29. Qiu, Y.; Xia, H.; Miao, J.; Huang, Z.*; Li, N.; Cao, X.; Han, J.; Zhou, C.; Zhong, C.; Yang, C.* Narrowing the Electroluminescence Spectra of Multiresonance Emitters for High-Performance Blue OLEDs by a Peripheral Decoration Strategy, ACS Appl. Mater. Interfaces. 2021, 13, 59035–59042.

30. Qi, Y.; Ning, W.; Zou, Y.*; Cao, X.; Gong, S.*; Yang, C.* Peripheral Decoration of Multi-Resonance Molecules as a Versatile Approach for Simultaneous Long-Wavelength and Narrowband Emission, Adv. Funct. Mater. 2021, 31, 2102017.

31. Qi, Y.; Cao, X.; Zou, Y.*; Yang, C.* Color-Tunable Tetracoordinated Organoboron Complexes Exhibiting Aggregation-Induced Emission for the Efficient Turn-On Detection of Fluoride Ions, Mater. Chem. Front. 2021, 5, 2353-2360.

32. Qi, Y.; Cao, X.; Zou, Y.*; Yang, C.* Multi-resonance organoboron-based fluorescent probe for ultra-sensitive, selective and reversible detection of fluoride ions, J. Mater. Chem. C. 2021, 9, 1567-1571.

33. Lu, G.; Wu, Z. G.; Wu, R.; Cao, X.; Zhou, L.*; Zheng, Y. X.*; Yang, C.* Semitransparent Circularly Polarized Phosphorescent Organic Light-Emitting Diodes with External Quantum Efficiency over 30% and Dissymmetry Factor Close to 10⁻², Adv. Funct. Mater., 2021, 31, 2102898.

34. Li, N.; Ni, F.; Lv, X.; Huang, Z.; Cao, X.; Yang, C.* Host-Dopant Interaction between Organic Thermally Activated Delayed Fluorescence Emitter and Host Material: Insight into the Excited State, Adv. Opt. Mater. 2021, 10, 2101343.

35. Huang, Z.; Huang, C.-W.; Tang, Y.-K.; Xiao, Z.; Li, N.; Hua, T.; Cao, X.; Zhou, C.; Wu, C.-C.*; Yang, C.* Chiral Thermally Activated Delayed Fluorescence Emitters For Circularly Polarized Luminescence And Efficient Deep Blue OLEDs, Dyes Pigm., 2022, 197, 109860.

36. Hua, T.^‡; Zhan, L.^‡; Li, N.; Huang, Z.*; Cao, X.; Xiao, Z.; Gong, S.*; Zhou, C.; Zhong, C.; Yang, C.* Heavy-Atom Effect Promotes Multi-Resonance Thermally Activated Delayed Fluorescence, Chem. Eng. J. 2021, 426, 131169.

37. Han, J.^‡; Huang, Z.^‡; Lv, X.; Miao, J.*; Qiu, Y.; Cao, X.; Yang, C.* Simple Molecular Design Strategy for Multiresonance Induced TADF Emitter: Highly Efficient Deep Blue to Blue Electroluminescence with High Color Purity, Adv. Opt. Mater. 2021, 10, 2102092.

38. Zhou, X.; Huang, M.; Zeng, X.; Zhong, C.; Xie, G.; Gong, S.; Cao, X.; Yang, C.* Sky-Blue Thermally Activated Delayed Fluorescence Polymers With π-Interrupted Polymer Mainchain Via Friedel-Crafts Polycondensation, Polymer 2020, 204, 122722.

39. Zhou, X.; Huang, M.; Zeng, X.; Zhong, C.; Xie, G.; Cao, X.; Yang, C.*; Yang, C.* Superacid-Catalyzed Friedel–Crafts Polyhydroxyalkylation: A Straightforward Method to Construct Sky-Blue Thermally Activated Delayed Fluorescence Polymers, Polym. Chem. 2020, 11, 3481.

40. Zhou, C.; Chen, W.-C.; Liu, H.; Cao, X.; Li, N.; Zhang, Y.; Lee, C.-S.*; Yang, C.* Isomerization Enhanced Quantum Yield of Dibenzo[a,c]Phenazine-Based Thermally Activated Delayed Fluorescence Emitters for Highly Efficient Orange OLEDs, J. Mater. Chem. C. 2020, 8, 9639-9645.

41. Yang, W.; Yang, Y.; Qiu, Y.; Cao, X.; Huang, Z.; Gong, S.*; Yang, C.* AIE-Active Multicolor Tunable Luminogens: Simultaneous Mechanochromism and Acidochromism with High Contrast Beyond 100 nm, Mater. Chem. Front. 2020, 4, 2047-2053.

42. Pathak, S. K.; Xiang, Y.; Huang, M.; Huang, T.; Cao, X.; Liu, H.*; Xie, G.; Yang, C.* Fused tetracyclic tris[1,2,4]triazolo[1,3,5]triazine as a novel rigid electron acceptor for efficient thermally activated delayed fluorescence emitters, RSC Adv. 2020, 10, 15523-15529.

43. Ni, F.^‡; Huang, C.-W.^‡; Tang, Y.; Chen, Z.; Wu, Y.; Xia, S.; Cao, X.; Hsu, J.-H.; Lee, W.-K.; Zheng, K.; Huang, Z.; Wu, C.-C.*; Yang, C.* Integrating Molecular Rigidity and Chirality into Thermally Activated Delayed Fluorescence Emitters for Highly Efficient Sky-Blue and Orange Circularly Polarized Electroluminescence, Mater. Horiz. 2021, 8, 547-555.

44. Lv, X.; Wang, Y.; Li, N.; Cao, X.; Xie, G.; Huang, H.; Zhong, C.; Wang, L.*; Yang, C.* Regulating The Photophysical Properties of Highly Twisted TADF Emitters by Concurrent Through-Space/-Bond Charge Transfer, Chem. Eng. J. 2020, 402, 126173.

45. Liu, H.*; Li, J.; Chen, W.-C.; Chen, Z.; Liu, Z.; Zhan, Q.; Cao, X.; Lee, C.-S.*; Yang, C.* Modulating The Acceptor Structure of Dicyanopyridine Based TADF Emitters: Nearly 30% External Quantum Efficiency and Suppression on Efficiency Roll-Off In OLED, Chem. Eng. J. 2020, 401, 126107.

46. Li, N.; Chai, D.; Chen, Z.; Zhou, C.; Ni, F.; Huang, Z.; Cao, X.; Xie, G.*; Li, K.; Yang, C.* Molecular Engineering by σ-Bond Spacer Enables Solution-Processable Host Materials for TADF Emitter towards High-Performance OLEDs, Chem. Eng. J. 2020, 396, 125276.